Hair

Caffeine

INCI: Caffeine · CAS 58-08-2

Caffeine is a plant-derived methylxanthine used in cosmetics as an antioxidant and stimulating active, popular in scalp, hair and eye-area products.

INCICaffeine
CAS58-08-2
Use leveltypically 0.5–3%
Solubilitywater-soluble (better in hot water)
pH / stabilitybroad; water-soluble (hot water)
RegulatoryListed in EU CosIng

What it does

  • Provides antioxidant protection.
  • Popular in scalp and hair products as a stimulating active.
  • Helps reduce the look of puffiness in eye-area products.

How it works

Caffeine is widely documented as an antioxidant and a vasoactive, stimulating compound. In eye products it is associated with a temporary reduction in the look of puffiness, and it is a common feature of scalp-and-hair products aimed at supporting the scalp. It penetrates reasonably well and is easy to formulate.

Use level

Typical use level
typically 0.5–3%

Commonly used at 0.5–3% across scalp, hair and eye-area products.

Formulation considerations

  • Water-soluble; dissolves more readily in warm water, then cool the batch.
  • Broadly compatible and stable.
  • Ensure full dissolution to avoid recrystallisation at high levels.

What it pairs with & what to avoid

Pairs well with

  • Rosemary extract (scalp/hair)
  • Niacinamide, peptides (eye area)
  • Hydrators

Use with care / avoid

  • Incomplete dissolution at high levels (crystallisation)

Regulatory status

Caffeine is listed in the EU CosIng database and is a well-established cosmetic ingredient.

Common questions

What does caffeine do in skincare?

It acts as an antioxidant and stimulating active; in eye products it is associated with a temporary reduction in the look of puffiness, and it is common in scalp/hair care.

What percentage of caffeine is used?

Typically 0.5–3%.

Is caffeine good for hair?

It is a popular scalp-and-hair active; it is best considered a supportive ingredient within a complete formula.

Related monographs

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